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Thursday, 12 October, 2017

Single-Site Photocatalytic H2 Evolution from Covalent Organic Frameworks with Molecular Cobaloxime Co-Catalysts

T. Banerjee, F. Haase, G. Savasci, K. Gottschling, C. Ochsenfeld and B. V. Lotsch -
Journal of the American Chemical Society, 10.1021/jacs.7b07489 (2017)

We demonstrate photocatalytic hydrogen evolution using COF photosensitizers with molecular proton reduction catalysts for the first time. With azine-linked N2-COF photosensitizer, chloro(pyridine)cobaloxime co-catalyst, and TEOA donor, H2 evolution rate of 782 μmol h–1 g–1 and TON of 54.4 has been obtained in a water/acetonitrile mixture. PXRD, solid-state spectroscopy, EM analysis, and quantum-chemical calculations suggest an outer sphere electron transfer from the COF to the co-catalyst which subsequently follows a monometallic pathway of H2 generation from the CoIII-hydride and/or CoII-hydride species.

pubs.acs.org/doi/abs/10.1021/jacs.7b07489